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St:_x6RS1_x x'`H2SiO3<H2CO3 EeB C0ݔ(WSm]xx-NSuS^ubNB\[v'lSirOb ;bkQё^\~~S^ SuSsa EeC D0\H2O2nR0Rx'`KMnO4nm-N Su'lS؏SS^ H2O2wQ g؏S'` yP[e z_:N2MnO4- +5H2O2+6H+ = 2Mn2+ +5O2!+8H2O EeD0 15 NRyP[e z_vfNQcknxv/f ANzkxxS^2Fe + 6H+ === 2Fe 3+ + 3H 2! B/lSݔnm-NReQǏϑv(l4lAl3+ + 4NH3H2O === AlO2 + 4NH4+ + 2H2O C\x'`'lSnNvxFe3O4 + 8H+ === 3Fe3+ + 4H2O Donwpp4lTǏϑvxx"lnmmT 2HCO3 + Ca2 + 2OH === CaCO3! + CO32 + 2H2O 0}TaV0 ,gyP[e z_vfNQ:NReQp0gf[uyP[S^vW@xwƋS[S^StvNS^(u _[f[usQlNSf[ gsQyP[e z_vfNQ NOۏf[u(WwƋNb0Ǐ zNelI{ebvhQbSU\0 0ċ^0 ANzkxxS^Fe^ubFe 2+ B/lSݔnm-NReQǏϑv(l4l ^Q\OAl3+ +3NH3H2O Al(OH)3! + 3NH4+ C\x'`'lSnNvxFe3O4 + 8H+ = Fe2+ +2Fe3+ + 4H2O Donwpp4lTǏϑvxx"lnmmT onwpp4l/fϑ\v [:N 1mol +T2mol OH N2mol HCO3 EQRS^0@bNDcknx 0bU\^0 yP[e z_vfNQؚN/fW@x /f-Nf[Sf[f[`Nv͑pwƋ hQbccyP[e z_vfNQel g)RNcؚf[u[nmbqr` NSf[S^v,g(vƋ SU\f[uv8h_ }{Q0 16[[(uNaOHVSOM6R1.0 molL 1vNaOHnm240mL0 NRlcknxv/f AM6Rnme(u0R240mLv[ϑt BM6RnmeyϑNaOHVSOv(ϑ:N9.6 g C[[eOƉ;R^~ @bM6RvNaOHnmSm^OP'Y D[[GdSYnT mbNON;R^~ QR4l;R^~ 0}TaV0,gNM6RNaOHnm:Ǹof ;N[W@xv[wƋ YNhV[ϑtvĉFe2 >Br BSmTnm-NFeBr2vir(vϑ:N3 mol CSnm-Nn(Fe2 )6"n(I )6"n(Br )46"16"3 DS_eQ1 mol Cl2e nm-NSuvS^:N2Br + Cl2 === Br2 + 2Cl 0}TaV0,g'}[T|'lS؏St SOs'lS؏Sv^l^(u0vN2Fe2+ Br2===2Fe3+ 2Br 2Fe3+ 2I ===2Fe2+ I2ُNS^N[:NW@x ^(u'lSBRv'lS'`:_N'lSNir,؏SBRv؏S'`:_N؏SNirvSt Q[mSё^\yP[N^ё^\'lS'`0؏S'`I{vsQ'`(S^(u09hncVa~*jPWhpencRg$ReOo` gf[u[$ReyP[vS^HQTz^,6qT9hncVa$ReSRS^vTyP[vir(vϑ _[f[usQlN'lS؏S gsQv8^Ƌ NOۏf[u(WwƋNb0Ǐ zNelI{ebvhQbSU\ SU\f[u8h_ }{Q0 0ċ^0(W'lS؏SS^-N'lSBRv'lS'`:_N'lSNir,؏SBRv؏S'`:_N؏SNir, 9hnce z_2Fe2+ Br2===2Fe3+ 2Br $Re,؏SBRFe2+v؏S'`:_N؏SNirBr , @bN؏S'`: Fe2+Br 'lSBRBr2v'lS'`:_N'lSNirFe3+,@bN'lS'`Br2Fe3+, Tt$Re,؏S'`: I Fe2+,'lS'`Fe3+I2@bN؏S'`I >Fe2+>Br , 'lS'`Br2Fe3+I2 A y/fv; B yeQCl2T, I HQ'lS,vQ!k/fFe2+,gT/fBr ,(WeQCl2vϑ:N0-1molvǏ z-N, I Ng'YϑM0R0,sS_0RI vir(vϑ:N2mol,eQCl2vϑ:N1-3molvǏ z-N, Fe2+N4molM0R0, Fe3+vϑnX'Y,@bN+T gFe2+qQ4mol,(WeQCl2vϑ:N3-6molv Ǐ z-NBr N6molM0R0,@bNBr vir(vϑ/f6mol,sSFeBr2vir(vϑ:N3mol, @bNB y/fcknxv; C y1uBSNwS, I vir(vϑ:N2mol, Fe2+/f4mol, Br vir(vϑ/f6mol n(Fe2+)6"n(I )6"n(Br )26"16"3 @bNC y/fv. 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ga|-N@b+TxSP[v*Npe:N______________0xSP[v(ϑ:N______________0 3 l\m-Na|vir(vϑSm^:N_______________0 OYu2MO gHepeW[ 0}TaV0,ggf[uؚ-NSf[vsQirtϑvvsQ{ Te؏[u{USSeOo`v^N] gwƋT͑~(WLu`X-NRgT㉳QvR0 0ċ^0 )R(ur^agN@bcOva|Sf[_{Qa|vid\(ϑ:N126+112+166=180g mol 10 9hnc(ϑHQ{Qa|ir(vϑn=36.0 g180g mol 1=0.2mol xSP[v*NpeN=0.2mol6NA=1.2NAb7.22410230 )R(uh~{@bcOvOo`Swa|v(ϑ:N25g a|nmvSOy:N500ml Vdkl\m-Na|vir(vϑSm^ 217R A0B0C0DGW:N-Nf[Sf[8^ir( NGW+T TNyCQ } A/fUS(0[NKN gYVvlSsQ| 1 Av0qrS^:NĞr S^b$/f5uBnm6RS/llv]N6RlDvO T:N\ςSb RCvSf[_:N QQDv(u 0NQNy 2 Dir(wQ g$N'` a$0b$S^GW(u:_xnm c$S^eeQǏϑvNy_w)n[He^vlSO0AvSP[~g:yaV/f Cv4yP[:N QQS^c$vyP[e z_____________________________________0 210}TaV0 ,ggir(lSsQ|v^(uT'`(^(u ;Ng0ݔSvQSTir'`(S'`(v~T^(u0ǏlSsQ|V g0ݔSvQSTir'`(00qrS^0/lx]N0yP[e z_0Sf[_0ir(O T0(uI{;Nr^wƋ0RB\b N[f[ucS08T6e0teTOo`vR (ucknxvSf[(uhRg㉳QvǏ zT~g S[VPv‰[`~R0 0ċ^0 1 A0qrS^:NĞr A/fUS( EeA:N 5uBnm6RS/llv]N6RlsS:N/lx]N ubirdCl2Y؏ gH2TNaOH0A0B0C0DGW:N-Nf[Sf[8^ir( NGW+T TNyCQ } EeC:NNaOH DvO T:N\ςSb vQ(u/fq6R|p@b(uvSu|;NbRKNN (W;Su N [/fluÀxǏYvNyoBR0EeDv(u/fSu|TtT{HhGW~R 2 Dir(wQ g$N'`SNcKmD/f"l'lSݔ0a$0b$S^GW(u:_xnm $ReA:Nݔ ScKma$/fݔN:_xnmS^ubOPݔxv EeAvSP[~g:yaV/f Cv4yP[:NOPݔx9hyP[bAlO2 0 c$S^/feQǏϑvNy_w)n[He^vlSO Eec$/fOPݔxNN'lSxT4lS^ub"l'lSݔlm c$S^vyP[e z_AlO2 +CO2+2H2O === Al(OH)3!+ HCO3 227R YV/f-Nf[Sf[-N8^(uNmTirvRyTc~vňn 9hncňnVT{  1 NhV`$v Ty__________0 2 N/lSnm-N_0R/lSVSO bňn________(kXW[k N T) 3 (WňnB-NReQ10 mLx4l 6qTQleQ5 mL CCl4 v}Yst^X cd\OĉRS Y/caTYn0(WRme:NOmSOz)Rn N Sb_ Nze^XMR ؏^ۏLvwQSOd\O/f_________________________________________________________0RmT :N_0Rxv^V6eCCl4S bňn______0 4 |v-N+TCa2 0Mg2 0SO42 I{Bg( c~TMb~T)R(u0|vc~vek g`$ReQǏϑvNa2CO3nm0 a$ReQǏϑvBaCl2nm0 b$ReQǏϑvNaOHnm c$(uϑvxnmvpHI{N70 d$n0 e$Ǐn0 f$S cknxvd\Oz^/f________(kX yW[k)0 ad$a$b$`$e$c$f$ bd$`$a$b$e$c$f$ cd$a$`$b$c$e$f$ dd$b$a$`$e$c$f$ 220}TaV0 ,gN-Nf[Sf[-N8^(uNmTirvRyTc~vňn:N}SO ~TgSf[[ gsQwƋ Sb[NhV0[d\O0ir(h0[eHhI{N|vc~vd\Oz^ gf[uRgwQSO0㉳QvR0SteTNS^(uOo`vR0[cvzR0 0ċ^0 (1)ňnA-NNhV`$v Ty/fpt0 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