ࡱ> )` Rdobjbjg{{S%-GGG8G4&Ihx&IRPJ"rJrJrJRRRwwwwwww{h}:w-WY&RRWYWYwrJrJ"xmmmWYnrJrJwmWYwmm: r,rrJI 0 %^Gj7r td8x0hxArR0~k0~rrT0~rRSmbTTiRRRwwl^RRRhxWYWYWYWYd(V?dV? l]N-N2017-2018 Nf[gg-NՋwS ؚNSf[ 2017.11.16 v[SP[(ϑ(1 #12 N 14 O 16 S 32 Cl 35.5 Cu 64 Pb 207 Ag 108 N0 bkS gN*NT{Hh k3R qQ54R0 1 NRagNN[OS^sR_v/f`$XRS^irvir(vϑ a$GSؚ)n^ b$)\S^[hVvSOy c$ReQubir d$ReQPSBR AhQ B`$a$d$ Ca$ Da$b$ 2S^A+3BP%2C+2D(WVy N T`Q NvS^sR+R:N `$ (A)=0.15mol" L 1" s 1 a$ (B)=0.6mol" L 1" s 1 b$ (C)=0.4mol" L 1" s 1 c$ (D)=0.45mol" L 1" s 10 S^ۏLv_baz^:N( ) Aa$c$b$`$ Bc$b$=a$`$ C`$=a$=b$=c$ Del$Re 3 NRlcknxv/f( ) AQ/f>epS^/fSv V:N8TpS^/f^Sv BSS^vqN[X'Y ^SS^vqN[Q\ C8^)n N S^C(s)+CO2(g)=2CO(g) NSۏL RS^v%H0 DS^2Mg(s)+CO2(g)=C(s)+2MgO(s)SۏL RS^v%H0 4pogA-Nv>e0.1 mol/LvH2SO4nm pogB-Nv>e0.1 mol/LvCuCl2nm($NynmGWϑ) ~bvňnYV@b:y0 NRl Ncknxv/f(00) AA:NS5u`l B:N5u`l BA:N5u`l B:NS5u`l CS_Apog-NNu0.1 mollSOe Bpog-NNulSOvir(vϑ_N:N0.1 mol D~ǏNke Bpog-NnmvpHX'Y 55uCuSO4nme 傁0RN N NpBl`$3g(ϑQ\a$4g(ϑXRb$nm-Nc(Cu2+) NS0S (uv5ug/f( ) A~ܔ\O3g +TZn0AgvܔTё\O4g B+TZn0AgvܔTё\O3g ~ܔ\O4g C(u~\O3g (u~ܔ\O4g D(uwX\O3g (u`'`5ug(Pt)\O4g 6 NRTňn-Nv g0.1mol/LvNaClnm >enN[eT ňn-NvVWWv Tv Gr Ps1u_0Rbavcknxz^/f( )  Ab$`$c$a$ B`$a$c$b$ C`$a$b$c$ Da$`$c$b$ 7 NRT~S^-N ^\NSS^vN~/f A2H2O2H2!+O2! 2H2+O22H2O BNH3+CO2+H2ONH4HCO3 NH4HCO3NH3!+H2O!+CO2! 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(2)2R ]N N(uCO2TH2S^TbN2u0]w CO2(g)+3H2(g) CH3OH(g)+H2O(g)%H1-49.1kJ/mol 2CH3OH(g) CH3OCH3(g)+H2O(g) %H2-24.5kJ/mol QQCO2(g)TH2(g)lS:NCH3OCH3(g)TH2O(g)vpSf[e z_________0 (3)2R N2uqe5u`lwQ gϑlSsؚ05uϑ'Yvyrp ^l^(u NyN2u'll5u`l(5u(:NKOHnm)vgS^_:N________ 235R ]wSS^CO(g)+H2O(g) INCLUDEPICTURE "http://www.pratice.net/images/symbols/5.gif" \* MERGEFORMATINET CO2(g)+H2(g) s^a8^pe Nh )n^/!5007008501 000s^a8^pe2.51.71.00.61 S^H________0kX  b  0 2 850!e TN[yV[v[핹[hV-N TeEQeQ1.0 mol CO03.0 mol H2O01.0 mol CO2Txmol H2 傁O NS^_YeckTۏL Rx^nvagN/f 0x5.0 S_S^0Rs^ae n(H2) 0 N0{6R 24\0.1 L+T g0.02mol CuSO4T0.01molNaClvmTnm(u`'`5ug5u05uNkeT 4g N_0R0.01 mol Cu SN5ug3g gQvlSO/fNHNSOyY\kGShQrQ 0BlQQ{Ǐ z l]N-N2017-2018 Nf[gg-NՋwS ؚNSf[ 2017.11.16 ST{Hh 12345678910CBCBADCDAD11121314151617181920ABCADCAB 19. 4R 10.0 0 kxxSm^ 20. 7R (1)2 1 3 2 (2R) (2) l` V`b~m` l` 3R (3)>ep 2R 21.9R I . 8T'l 2Clc+2H2O  2OHc+H2!+Cl2!1+ 2R a!. \N D O2 O2 + 4H+ + 4ecP% 2H2O 22.15R (1) `$0.030.56 4R a$BC 2R b$MNO  4R (2) 2CO2(g)+6H2(g)  CH3OCH3(g)+3H2O(g) %H= -122.7 kJ/mol3R (3) CH3OCH3 - 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