ࡱ> )` RFbjbj2X{{% 8* t $x(. P "r r r '''''''$)h,r'EEEE'r r 2(3'3'3'E< r r '3'E'3'3'3'r  $3's'TH(0x(3',A&,3'3',G',:3'S''&dx(EEEE $   ؚNSf[WO~`N 2019-12-28 10  TN[ϑvFe0FeO0Fe2O30Fe3O4vmTir-NReQ150 mL 4molL 1vz]xxp`}YOmTir[hQn >eQ2.24 L NO(hQrQ) _@b_nm-NReQKSCNnm e~rQs0(uϑvH2(WRpagN N؏Sv T(ϑvmTir @b_0Rvvir(vϑ:N(00) 0 A0.21 mol0 B0.25 mol0 C0.3 mol0 D0.35 mol 20 2019fkIlNg (ul(;NbR:NFe2O30FeOT\ϑFe)6RY~s|F3O4 vAm z:yaVY N  INCLUDEPICTURE "http://www.pratice.net/t_pic/21/18976_1.gif" \* MERGEFORMATINET  NRSv/f 0 A.:Ncؚek`$vS^s SǑSdb0GS)nI{ce 0 B.eka$-N ;NS^vyP[e z_/f2Fe3++Fe===3Fe2+ 0 Cekc$-N S^[bTiRYOvH2O2edS 0 Dekd$-N  Ry S+Tvd\O gǏn0mm 30 2016 Nwmؚ gv'lSirFexO 1.52 gnNϑvx-N T@b_nm-NeQhQrQ N112 ml Cl2 p`}Y\Fe2+[hQ'lS0xeQlSO 0 DT勶nm-NeQǏϑCl2 S^vyP[e z_ 2Fe2+ 4Br 3Cl2==2Fe3+ 2Br2 6Cl 60 2014q\Nؚ I{(ϑv NRir(Nϑz]xxS^ >eQNOir(vϑgYv/f 0 AFeO00000 B. Fe2O30000 C. FeSO40000 D0Fe3O40000 70 2014[_ NR gsQFe2(SO4)3nmvScknxv/f 0A勶nm-N K+0Fe2+0C6H5OH0Br SN'YϑqQX[ 0BTKInmS^vyP[e z_Fe3++ 2I = Fe2++ I2 0CTBa(OH)2nmS^vyP[e z_ Fe3++ SO42 + Ba2++ 3OH = Fe(OH)3!+ BaSO4! 0D 1L0.1mol/L勶nmTϑvZnEQRS^ ub 11.2gFe 80 2014l]Nh gsQFeSvQSTirvRlSsQ|YV@b:y0 NRl Ncknxv/f 0000000 INCLUDEPICTURE "http://www.pratice.net/t_pic/21/17090_1.jpg" \* MERGEFORMATINET  0 A`$-NkxxvSm^SN:N98%0000000 Ba$-NՋBRSN/f(l4lbNaOHnm 0 Cb$-Nd\O:NSSm)0QtS~vf000 0 DXN[+T gSO2 90 2013 Nwmؚ gnmS+T gCl 0SO42 0CO32 0NH4+0Fe3+0Al3+TK+0S勶nm100mL ReQǏϑNaOHnm Rp _0R0.02mollSO TeNu~rlmǏn mm |pp _0R 1.6gVSOT Nnm-NRϑBaCl2nm _0R 4.66g NnNvxvlm01udkSwSnm-N 0A\X[(W5yyP[ 0 BCl N[X[(W NcCl e"0.4mol/L 0CSO42 0NH4+0N[X[(W Cl S NX[(W 0DCO32 0Al3+N[ NX[(W K+SX[(W 100 2009t^10g1e (W)Y[^:W>NLN͑vV^uQN_ U\sNbV:_'Yv~TVR vQ-NfWKQvU\:yeu/fN*N]'YvNp0fWKQv6R Pge;N/fTyё^\vTё O/fvQ-NASR͑vNy0 NRsQNvl-N cknxv/f 0ACQ }^\NǏ!nCQ } vQSP[^pe:N26 0BUS(NSmkxx(W8^)n N NS^ 0CUS(SwQ g؏S'` vQ3yP[SwQ g'lS'` 0DNv TSm^vvxS^ub"llvs ~kuv_ 110 gf[ut[2uvvekYV@b:y  INCLUDEPICTURE "http://www.pratice.net/t_pic/21/16064_1.jpg" \* MERGEFORMATINET  NR~cknxv/f 0A2u-NN[ gFe3 0000 BN-NN[ gFe3 0CYN:NAgIlm0 0000 D2uN[:NFeBr2nm 120 TN[ϑvFe0FeO0Fe2O3vmTir-N ReQ100 mL 1 mol/Lvvx p`}YOmTir[hQn >eQ224 mL(hQrQ N)vlSO0@b_nm-NReQKSCNnme@~rQs mTir-NCQ }v(ϑRpe:N 0A81.4%0 B77.8%00 C68.6%0 000 Del{ 130 2019VnSkQ!hNT :NNcvz0ܔSvQSTirv'`( g Tf[v^ۏLN NR[0 NRl-Nv/f  INCLUDEPICTURE "http://www.pratice.net/t_pic/21/19057_1.jpg" \* MERGEFORMATINET  0 Aؚ)nRpňn-NSuvS^:N3Fe(s) 4H2O(g)0ؚ)n0Fe3O4(s) 4H2(g) 0 BZ~FhY[ bvňn/f2u 0 C[e\erܔNRp SўTQpŏ8OeQՋ{-N S‰[0RܔN1uўrS:N~r 0 D[T S(uݔ|(Wؚ)n N؏Sst{-NvVSO_US( 140 \CuGr>eeQ0.1 molL 1FeCl3nm-N S^N[eTSQCuGr @b_nmQ-Nvc(Fe3 )c(Fe2 )23 NR gsQl-Ncknxv/f 0 AQ-Nn(Cu2 )n(Fe2 )12 0 BS^-Nly5uP[:N0.04 mol 0 CnmQkSnmX͑N 1.28 g 0D 3c(Fe3 ) 2c(Fe2 @Bhjlntvxz d h ʳggggMg8g)h6a5B*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph/h6ah6a5B*KHOJQJ^JaJo(ph3h6ah6a5B*KHOJPJQJ^JaJo(ph-h6a5B*KHOJPJQJ^JaJo(ph7h6ah6a5B*CJ,KHOJPJQJ^JaJ,o(ph1h6a5B*CJ,KHOJPJQJ^JaJ,o(phBtx "024688@@@@ $$1$Ifa$gd6a $1$a$gd6$ 1$WD/` a$gd6a $1$a$gd6a $1$a$gd6aE F     4 6 , 0 Z ^ p t x |  X Z f j ~     $ ( ηΐΐvvΐΐvΐΐvv2h6ah6a5B*H*KHOJQJ^JaJo(ph)h6a5B*KHOJQJ^JaJo(ph#h6ah6a5KHOJQJ^JaJ,jh6ah6a5KHOJQJU^JaJ/h6ah6a5B*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph.( * , . 8 : J N r v | ~ $&*04<>PR^`z|>B\^rtz~δΟδδδΟδδδΟΟδδΟΟΟδδ)h6a5B*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph/h6ah6a5B*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph>2468PRdfhj"&02:>FH^`vx|ͳ)h6a5B*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph/h6ah6a5B*KHOJQJ^JaJo(ph>"pv0246:>jl Ҹҡx^D^D2h6ah6a5B*H*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph,j^h6ah6a5KHOJQJU^JaJ#h6ah6a5KHOJQJ^JaJ,jh6ah6a5KHOJQJU^JaJ2h6ah6a5>*B*KHOJQJ^JaJo(ph/h6ah6a5B*KHOJQJ^JaJo(ph)h6a5B*KHOJQJ^JaJo(ph"(*,26<@DF6PR\dfz|ͳͳͳͳͳ)h65B*KHOJQJ^JaJo(ph)h6a5B*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph/h6ah6a5B*KHOJQJ^JaJo(ph,jlnp$&(*.6bd騎t_tt_J)h6a5B*KHOJQJ^JaJo(ph)h65B*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph/h6ah6a5B*KHOJQJ^JaJo(ph,j;xh6ah6a5KHOJQJU^JaJ#h6ah6a5KHOJQJ^JaJ,jh6ah6a5KHOJQJU^JaJdfhnrVZ:>NR^bҺqWWWWW2h6ah6a5B*H*KHOJQJ^JaJo(ph2h6ah6a5>*B*KHOJQJ^JaJo(ph2h6ah6a5B*H*KHOJQJ^JaJo(ph)h6a5B*KHOJQJ^JaJo(ph/h6ah6a5B*KHOJQJ^JaJo(ph,jh6ah6a5KHOJQJU^JaJ,j^h6ah6a5KHOJQJU^JaJ"blprv44444444444&5(5*5,56585:5<5^5`5b5d5n5p5r5t5555586:6縶s#h6ah6a5KHOJQJ^JaJ,jh6ah6a5KHOJQJU^JaJ2h6ah6a5B*H*KHOJQJ^JaJo(phU2h6ah6a5B*H*KHOJQJ^JaJo(ph)h6a5B*KHOJQJ^JaJo(ph/h6ah6a5B*KHOJQJ^JaJo(ph-) 2c(Cu2 )0.1 mol/L 150 kxxN/fNy͑vS]Se SN6RYN|Rir(Y NV@b:y 0 NRlv/f 0Ax_kxx4lNuFe(OH)3SO S(u\OQ4lBR 0B:N2bkNH4HCO3R uNFeCO3(WNO)n^ NۏL 0CS(uKSCNnmh(NH4)2Fe(SO4)2/f&T'lS 0D8^)n N (NH4)2Fe(SO4)2(W4l-Nvn㉦^kFeSO4v'Y  INCLUDEPICTURE "http://www.pratice.net/t_pic/21/16734_1.gif" \* MERGEFORMATINET  160 \a gT'lSvmTirReQ800 mL pH1vvx-NEQRS^T vxhQ萈m >eQhQrQ NlSO 0.224 L0R NR$Re-Ncknxv/f 0ASmTir-Nn(Fe)n(Fe2O3)21 0BTnm-NneQervKSCNnm >f@~r 0Cel{QSmTirv(ϑ 0Ddkenm-NFe2 TFe3 vir(vϑKNk:N31 190 2012^]N!j NRlcknxv/f 0AFe(WN[agN NN4lS^ubH2TFe(OH)3 0BFe3O4nNvxTReQQnKSCNnm nm>f~r 0CFeCl2nmr^|ppT_0RFeCl2VSO 0DFeCl3qTnmneQNaOHnm-NS6RYFe(OH)3SO 170 2013\g+g u-N+TxTkxI{CQ }0Sf[tQ\~[gu7hTۏLNcvz09hncBlVT{ NR0 Iu-NxTkxCQ }v['`h cYVňnۏL[9YcNhV]euS kXcSW[kNS SN[sxTkxCQ }vh0  INCLUDEPICTURE "http://www.pratice.net/t_pic/20/15809_1.jpg" \* MERGEFORMATINET  1 NhVXv Ty/f00000000000ňnb$0d$-NՋBRv T ňnc$-Nv>evՋBR/f00000 2 QQ2u-NS^vSf[e z_000000000000000 3 Ygddňnb$c$d$ &Tnxu7hT-NxCQ }vX[(W0000000 t1u/f0000000000000 IIu-Nx0kx(ϑRpevKm[ 4 2u Tf[:N N NňnSN|euKm[7hT-Nxv+Tϑ0yS7hTw1gۏL[ EQRS^T Km_ňne$-Nubvlm:Nw2g 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